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Photochemical Smog

The Chemistry of Photochemical Smog | |
|Key Concepts                                                                                                                                   |
|Photochemical smog is a type of air pollution produced when sunlight acts upon motor vehicle exhaust gases to form harmful substances such as |
|ozone (O3), aldehydes and peroxyacetylnitrate (PAN).                                                                                           |
|Ozone causes breathing difficulties, headaches, fatigue and can aggrevate respiratory problems.                                               |
|The peroxyacetylnitrate (CH3CO-OO-NO2) in photochemical smog can irritate the eyes, causing them to water and sting.                           |
|Ozone Production                                                                                                                               |
|Motor vehicles produce exhaust gases containing oxides of nitrogen such as nitrogen dioxide (NO2) and nitric oxide (NO).                       |
|At the high temperatures of the car's combustion chamber (cylinder)or during lightning,nitrogen and oxygen from the air react to form nitric   |
|oxide(free radical) (NO):                                                                                                                     |
|N2(g) + O2(g) -----> 2NO(g)                                                                                                                   |
|                                                                                                                                               |
|Some of the nitric oxide (NO) reacts with oxygen to form nitrogen dioxide (NO2):                                                               |
|2NO(g) + O2(g) -----> 2NO2(g)                                                                                                                 |
|...

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